Metal alloy clusters Cu.Sb, and Cu.Bi,,, are produced by a gas aggregation source and investigated by time-of-flight mass spectrometry following ionization with a KrF excimer laser. Two types of the magic numbers are observed in their cluster ions: magic numbers corresponding to jellium shell closin
โฆ LIBER โฆ
Antimony and Bismuth Oxide Clusters: Growth and Decomposition of New Magic Number Clusters
โ Scribed by France, M. R.; Buchanan, J. W.; Robinson, J. C.; Pullins, S. H.; Tucker, J. L.; King, R. B.; Duncan, M. A.
- Book ID
- 127304041
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 227 KB
- Volume
- 101
- Category
- Article
- ISSN
- 1089-5639
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Gas-phase metal clusters of antimony, bismuth, or antimony-bismuth alloys are prepared by laser vaporization and probed with UV laser photoionization in a time-of-flight mass spectrometer. Unusual size distributions are observed, ending at five-atom clusters. Fragmentation processes are extremely ef