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Anomeric effect on acidity; experimental and theoretical studies on proton abstraction at anomeric center of 1,5-anhydro-4,6-O-benzylidene-2,3-dideoxy-3-C-nitro-D-hex-2-enitol

โœ Scribed by Tohru Sakakibara; Tomohisa Nishitani; Akinori Seta; Toshio Nakagawa


Book ID
108382230
Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
255 KB
Volume
32
Category
Article
ISSN
0040-4039

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Reactions of the title compounds with several nucelophiles suggested that the ring oxygen atom (0-5) accelerated the reactivity of the nitro alkene moiety, but scarcely affected the stereoselectivity of the nucleophilic attack.