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Anomeric and conformational deuterium isotope effects in saturated sulphur and nitrogen heterocycles

✍ Scribed by Anet, Frank A. L.; Kopelevich, Max

Book ID
118042464
Publisher
The Royal Society of Chemistry
Year
1987
Tongue
English
Weight
266 KB
Volume
8
Category
Article
ISSN
0022-4936

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πŸ“œ SIMILAR VOLUMES

Deuterium isotope effects as a conformat
Deuterium isotope effects as a conformational probe in cyclic and acyclic ketones
✍ Stefan Berger; Bernd W. K. Diehl πŸ“‚ Article πŸ“… 1988 πŸ› John Wiley and Sons 🌐 English βš– 516 KB

Cyclic ketones from cyclobutanone to cyclohexadecanone were labelled with deuterium in the a-position. The deuterium isotope effect on the ''C NMR spectra was measured and in some cases was indicative of perturbation of conformational equilibrium. Similar effects were observed with acyclic ketones.