Anomalous chemiluminescence in reactions of alkali atoms with C2Cl4 and C2F4
โ Scribed by L.C. Balling; J.J. Wright
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 169 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0009-2614
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The absolute rate constants have been measured for several gas-phase chlorine atommolecule reactions a t 25OC by resonance fluorescence. These reactions and their corre- sponding rate constants in units of cm3 mole-' sec-l are: The effects of varying the substrate pressure, total pressure, light in
Rate constants for the reactions of atomic oxygen ( 0 3 P ) with C&3F, C&IaCl,C@3Br, 1, l-CzHzFz, and I ,2-C&IzFz have been measured at 307' K using a discharge-flow system coupled to a mass spectrometer. The rate constants for these reactions are (in units of 1011cm3mole-1s-1)2.63 &0.38,5.22 =tO0.2