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Anomalous behavior of rigid cinchona alkaloids in the enantioselective hydrogenation of ethyl pyruvate in an aprotic solvent

✍ Scribed by József L. Margitfalvi; Emilia Tálas


Book ID
108055125
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
319 KB
Volume
301
Category
Article
ISSN
0926-860X

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✍ György Szöllősi; Szabolcs Cserényi; Katalin Balázsik; Ferenc Fülöp; Mihály Bartó 📂 Article 📅 2009 🏛 Elsevier Science 🌐 English ⚖ 746 KB

The origin of rate enhancement in the enantioselective heterogeneous catalytic hydrogenation of ethyl pyruvate on Pt modified with the parent cinchonas, as compared to the unmodified Pt, was studied in a solvent mixture toluene/AcOH 9/1. Hydrogenation experiments were carried out in a continuousflow