The quasiclassical theory ofrotational relaxation processes is considered for CARS and Raman spectra of symmetric molecules. The kinetic equation is solved under arbitrary strength of collisions and the expressions describing the smoothed spectral contour are derived. The proposed processing of expe
Anomalies in the microwave spectra of symmetric molecules
β Scribed by Harald H Nielsen
- Publisher
- Elsevier Science
- Year
- 1951
- Weight
- 305 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0031-8914
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π SIMILAR VOLUMES
The effect of the noncorrespondence of normal coordinates on the Franck-Condon factors governing the appearance of non-totally symmetric vibrations in electronic spectra is examined. In a two-dimensional symmetry species containing vibrations 1 and 2, transitions such as 1 1 0 2 1 0 , 1 1 0 2 3 0 ,
The purpose of this paper is to present simple ideas about two kinds of infrared bands which are not considered in classical text books, namely hot bands and PAPE bands. The presentation is limited to molecules with \(C_{3 v}\) symmetry. PAPE bands are parallel bands with a perpendicular structure a