✍ Scribed by S. Asakura; T. Mukaibo
No coin nor oath required. For personal study only.
The mechanism of anodic passivation of platinum in a dehydrated LiCl-KC1 eutectic melt was studied by means of potential-sweep, galvanostatic, potentiostatic and potential-decay measurements.
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The electrolytic reduction and oxidation of TaCl, in the LiCl-KC1 eutectic meIt have been studied by chronopotentiometric and coulometric measurements at 500, 600 and 675°C. It has been found that the reduction occurs in two steps: a diffusion-controlled, reversible two-electron reaction from Ta(IV)
The variations of p02during the chlorination by phosgene of industrial aluminas and hexahydrated aluminium chloride were observed by means of an yttria-stabilized zirconia electrode. The curves obtained showed that chlorinations carried out in a continuous flow reactor, take place rapidly (30 min wi
The polarographic reduction wave of magnesium ion was confirmed in the purified lithium chloride-potassium chloride eutectic + magnesium chloride (7.20 Y lo-' mol/l) melt kept at 450" C. The half wave potential was -2.53V us the Pt-Pt'+ reference electrode, which was very close to the equilibrium po