Synthesis and Structure Elucidation of 8-Methyl-and 9-Methylexo-2-carbomethoxy-endo-tricyclo(5.2.1.02,6)deca-3,8-dien-5-ones. -The unseparable mixture of 1-and 2-methyl-tetrahydro-1,4-methanonaphthalenediones (I) and (II), resp., obtained by thermal cracking of methylcyclopentadiene dimer and trappi
✦ LIBER ✦
Annulated bicyclo[2.2.2]octenones: 9-hydroxy-9-chloromethyl-endo-tricyclo[5.2.2.02,6]undeca-4,10-diene-3-spiro(1′-cyclopropane)-8-one and 12-hydroxy-12-chloromethyl-endo-tricyclo [8.2.2.02,9]tetradeca-13-en-11-one
✍ Scribed by Mino R. Caira; Ashutosh V. Bedekar; Vishwakarma Singh
- Publisher
- Springer
- Year
- 1995
- Tongue
- English
- Weight
- 298 KB
- Volume
- 25
- Category
- Article
- ISSN
- 1572-8854
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## Abstract In view of the significance of steric compression in the base‐catalyzed intramolecular cyclization of polycyclic olefinic alcohols, the standard enthalpies of formation of __anti__^9,10^‐10 __endo__‐hydroxytricyclo [4.2.1.1^2,5^]deca‐3,7‐dien‐9‐one **(1)** and 9‐oxatetracyclo [5.4.0.0^3