Anisotropy effects on chain-chain interactions in stretched rubber
β Scribed by Gao, J.; Weiner, J. H.
- Book ID
- 126254986
- Publisher
- American Chemical Society
- Year
- 1991
- Tongue
- English
- Weight
- 901 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0024-9297
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## Abstract Dynamic mechanical properties of polyisobutylene, butyl rubbers, Paracril, __cis__β1,4βpolybutadiene, reinforced with EPC black, were determined in the temperature range β150β+170Β°C., in the frequency range 2β20 kcycles/sec. In the amorphous polymers, reinforcement causes an increase of
The pressures exerted by a polymer chain on the walls of an anisotropic confinement are anisotropic (Doi and Edwards [10]). At deformation rates larger than the inverse Rouse time of the polymer chain, chains are stretched and their confining tubes become increasingly anisotropic. In a tube model wi