✦ LIBER ✦

Anisotropic angular distribution of desorption of CO2 produced on Pd(110) surfaces

✍ Scribed by Tatsuo Matsushima

Publisher: Elsevier Science
Year: 1989
Tongue: English
Weight: 261 KB
Volume: 155
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(89)85331-x

No coin nor oath required. For personal study only.

✦ Synopsis

The desorption of CO, produced by the interaction of oxygen adatoms and CO admolecules on Pd( 110) was studied with angle-resolved thermal desorption. Four peaks of CO, formation appeared in the different coverage and temperature range. The desorption flux shows sharp and anisotropic angular distributions.

📜 SIMILAR VOLUMES

Angular distribution of the desorption o

Angular distribution of the desorption of carbon dioxide produced on palladium(111) surfaces at low temperature

✍ Tatsuo Matsushima; Hiromu Asada 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 292 KB

The desorpllon of CO, produced through the ~nw.rnctmn betueen oxygen adatoms nnd adsorbed CO on Pd(lll) surfaces was swdwd by rnwns of angle-resolved thermal desorptmn The nngulor dlstnbuwm nas enlrrmcly sharp and depended on the local configurahon of co-adsorbares around the sn1.z or CO, forma~ron

Tight-binding model of CO chemisorption

Tight-binding model of CO chemisorption on Pd/W (110) and Pt/W (110) surfaces

✍ Štěpán Pick 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 367 KB

We study the CO chemisorption on epitaxial Pd and Pt monolayers grown on W (110), by using a simple tight-binding self-consistent recursion method model. The tr donation, "rr back-donation and the adsorption energy are reduced by the substrate presence. For the atop site above Pd/W (110), however, t

Coupled chemical oscillators in catalyti

Coupled chemical oscillators in catalytic oxidation of CO on Pd(110) surfaces

✍ M. Ehsasi; O. Frank; J.H. Block; K. Christmann 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 391 KB

Gas phase coupling between two separate ( 1 IO)-oriented palladium single crystals is reported during reaction rate oscillations of CO oiidation. The oscillations were monitored by simultaneous measurement of work function changes on each crystal and of the combined CO2 production rates. With the on

The angular distribution of the product

The angular distribution of the product desorption and the orientation of terraces; the oxidation of carbon monoxide over platinum (110)(1×2) reconstructed surfaces

✍ Tatsuo Matsushima; Yuichi Ohno 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 315 KB

The angular distribution of the desorption flux of carbon dioxide produced on Pt( 110) ( 1 x 2) reconstructed surfaces was studied in both crystal azimuths of [ I i0 ] and [ 00 1 ] by means of angle-resolved thermal desorption. Heating the surface covered by CO and oxygen adatoms yields four peaks o

The influence of water on the chemisorpt

The influence of water on the chemisorption of CO2 onto Pd(110)

✍ R. Brosseau; T.H. Ellis; H. Wang 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 407 KB

A chemisorbed species of CO, has been observed on Pd( 1 IO) in the presence of coadsorbed water. It has been identified using vibrational spectroscopy as a bent, negatively charged CO;-species which has previously been observed on a number of clean and alkali metal predosed surfaces. The donation of

Coadsorption of CO and C2H4 on Pd(110).

Coadsorption of CO and C2H4 on Pd(110). Formation of a (3×2) mixed structure

✍ T. Takaoka; Y. Yasui; M. Sawada; T. Aruga; M. Nishijima 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 395 KB

The coadsorption of CO and C&I, on the Pd( 110) surface has been stu&ed by usmg low-energy electron dlffractlon (LEED), high-resolution electron energy loss spectroscopy (EELS) and thermal desorptlon spectroscopy (TDS) A (3 x 2) LEED pattern 1s observed for the (CO + C2H,)-coadsorbed Pd ( 1 IO) surf