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Anionic ring-opening polymerization of thiolactones

โœ Scribed by Overberger, Charles G.; Weise, Jurgen K.

Book ID
121190036
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
710 KB
Volume
90
Category
Article
ISSN
0002-7863

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Anionic ring-opening polymerization of s
Anionic ring-opening polymerization of silacyclobutane derivatives
โœ Kozo Matsumoto; Hironobu Shimazu; Masaki Deguchi; Hitoshi Yamaoka ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 236 KB ๐Ÿ‘ 2 views

Anionic polymerizations of 1,1-dimethylsilacyclobutane, 1,1-diethylsilacyclobutane and 1-methyl-1-phenylsilacyclobutane were investigated. Addition of 5 mol % of butyllithium to a solution of 1,1-dimethylsilacyclobutane in THF-hexane (1 : 1) at 048ะŠC provided poly(1,1-dimethylsilabutane) in 99% yiel