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Anionic Ring Opening of Norbornenes Fused to Heterocycles.

✍ Scribed by Antonio R. Hergueta; Carmen Lopez; Xerardo Garcia-Mera; Franco Fernandez


Publisher
John Wiley and Sons
Year
2005
Weight
19 KB
Volume
36
Category
Article
ISSN
0931-7597

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✍ Kozo Matsumoto; Hironobu Shimazu; Masaki Deguchi; Hitoshi Yamaoka πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 236 KB πŸ‘ 2 views

Anionic polymerizations of 1,1-dimethylsilacyclobutane, 1,1-diethylsilacyclobutane and 1-methyl-1-phenylsilacyclobutane were investigated. Addition of 5 mol % of butyllithium to a solution of 1,1-dimethylsilacyclobutane in THF-hexane (1 : 1) at 048ЊC provided poly(1,1-dimethylsilabutane) in 99% yiel