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Ring Opening of a Cyclopropyl Anion and Cycloaddition of the Allyl Anion

✍ Scribed by Dr. Gernot Boche; Dipl.-Chem. Diether Martens


Publisher
John Wiley and Sons
Year
1972
Tongue
English
Weight
230 KB
Volume
11
Category
Article
ISSN
0044-8249

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## Abstract Cyclopropanecarboxaldehyde (1 a), cyclopropyl methyl ketone (1 b), and cyclopropyl phenyl ketone (1 c) were reacted with [Ni(cod)~2~] (cod=1,5‐cyclooctadiene) and PBu~3~ at 100 °C to give Ξ·^2^‐enonenickel complexes (2 a–c). In the presence of PCy~3~ (Cy=cyclohexyl), 1 a and 1 b reacted