## Abstract The reactions of hydrated electrons (e~aq~^β^) with thymine dimer **2** and thymidine have been investigated by radiolytic methods coupled with product studies, and addressed computationally by means of BB1KβHMDFT calculations. Pulse radiolysis revealed that oneβelectron reduction of th
β¦ LIBER β¦
Ring Opening of a Cyclopropyl Anion and Cycloaddition of the Allyl Anion
β Scribed by Dr. Gernot Boche; Dipl.-Chem. Diether Martens
- Publisher
- John Wiley and Sons
- Year
- 1972
- Tongue
- English
- Weight
- 230 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0044-8249
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## Abstract Cyclopropanecarboxaldehyde (1βa), cyclopropyl methyl ketone (1βb), and cyclopropyl phenyl ketone (1βc) were reacted with [Ni(cod)~2~] (cod=1,5βcyclooctadiene) and PBu~3~ at 100βΒ°C to give Ξ·^2^βenonenickel complexes (2βaβc). In the presence of PCy~3~ (Cy=cyclohexyl), 1βa and 1βb reacted