𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Anionic Polymerization of (Meth)acrylates with Trialkylsilyl-protected Lithium N-Benzylamide

✍ Scribed by Kitaura, Takehiro; Kitayama, Tatsuki

Book ID
111776946
Publisher
Nature Publishing Group
Year
2007
Tongue
English
Weight
252 KB
Volume
40
Category
Article
ISSN
0032-3896

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

New initiator system for the anionic pol
New initiator system for the anionic polymerization of (meth)acrylates in toluene. IV. Random copolymerization of (meth)acrylates in toluene initiated by s-BuLi ligated by lithium silanolates
✍ Catherine Zune; Thomas Zundel; Philippe Dubois; Philippe Teyssié; Robert Jérôme 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 155 KB 👁 2 views

Copolymerization of binary mixtures of alkyl (meth)acrylates has been initiated in toluene by a mixed complex of lithium silanolate O(s-BuMe 2 SiOLi)O and s-BuLi (molar ratio Ͼ 21) formed in situ by reaction of s-BuLi with hexamethylcyclotrisiloxane (D 3 ). Fully acrylate and methacrylate copolymers

Anionic polymerization of primary acryla
Anionic polymerization of primary acrylates as promoted by lithium 2-(2-methoxyethoxy) ethoxide
✍ N. Nugay; T. Nugay; R. Jérôme; Ph. Teyssié 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 851 KB

Some primary acrylates, such as methyl, ethyl, n.-butyl, and n-nonyl acrylate (MA, EA, nBuA and nNonA, respectively) have been anionically polymerized by using diphenylmethyl lithium (DPMLi) as an initiator, in the presence of a chelating p-u dual ligand, i.e., a polydentate lithium alkoxide, at low

Mechanism of anionic polymerization of (
Mechanism of anionic polymerization of (meth)acrylates in the presence of aluminium alkyls, 2. Kinetic investigations with methyl methacrylate in toluene
✍ Helmut Schlaad; Axel H. E. Müller 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 366 KB

## Abstract The kinetics of the polymerization of methyl methacrylate initiated by lithium alkyls (__tert__‐butyllithium or ethyl α‐lithiobutyrate) was investigated in the presence of aluminium alkyls (triethylaluminium or triisobutylaluminium) in toluene at −78°C. The rate of polymerization decrea

Study of the propagation centre in the a
Study of the propagation centre in the anionic polymerization of (meth)acrylic monomers, 7. Study of the interaction of the living dimer with lithium tert-butoxide in tetrahydrofuran
✍ Jaroslav Kříž; Jiří Dybal; Miroslav Janata; Lubomír Lochmann; Petr Vlček 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 846 KB

## Abstract Using ^1^H, ^6^I i, ^7^Li and ^13^C NMR, di‐__tert__‐butyl 2‐lithio‐2,4,4‐trimethylglutarate (A) as a dimeric model of the living poly(__tert__‐butyl methacrylate) is shown to form well‐defined aggregates with lithium __tert__‐butoxide (B) in tetrahydrofuran. The prevailing aggregates w

Ligated anionic block copolymerization o
Ligated anionic block copolymerization of methyl methacrylate with n-butyl acrylate and n-nonyl acrylate as promoted by lithium 2-(2-methoxyethoxy) ethoxide/diphenylmethyllithium
✍ N. Nugay; T. Nugay; R. Jérôme; Ph. Teyssié 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 152 KB 👁 1 views

Poly(methyl methacrylate-b-n-butyl acrylate) (PMMA-b-Pn-BuA) and poly(methyl methacrylate-b-n-nonyl acrylate) (PMMA-b-Pn-NonA) diblock copolymers have been successfully synthesized by the sequential anionic polymerization of methyl methacrylate (MMA) and the n-alkyl acrylate (n-BuA or n-NonA), in a