Anionic Polymerization of (Meth)acrylate Monomers Initiated with Ligated Systems, Metalloporphyrins and Lanthanocenes
✍ Scribed by Petr Vlcek
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 11 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Copolymerization of binary mixtures of alkyl (meth)acrylates has been initiated in toluene by a mixed complex of lithium silanolate O(s-BuMe 2 SiOLi)O and s-BuLi (molar ratio Ͼ 21) formed in situ by reaction of s-BuLi with hexamethylcyclotrisiloxane (D 3 ). Fully acrylate and methacrylate copolymers
## Abstract The polymerization of acrylic acid by the redox system ammonium persulphate/sodium sulphite was studied under a variety of conditions. The obtained results indicate that the total conversion is determined by the concentrations of (NH~4~)~2~S~2~O~8~ and Na~2~SO~3~, as well as by the degr
## Abstract Poly(dimethylsiloxane)(PDMS)‐based triblock copolymers were successfully synthesized via atom transfer radical polymerization (ATRP) initiated with bis(bromoalkyl)‐terminated PDMS macroinitiator (Br‐PDMS‐Br). First, Br‐PDMS‐Br was prepared by reaction between the bis(hydroxyalkyl)‐termi
## Abstract Using ^1^H, ^6^I i, ^7^Li and ^13^C NMR, di‐__tert__‐butyl 2‐lithio‐2,4,4‐trimethylglutarate (A) as a dimeric model of the living poly(__tert__‐butyl methacrylate) is shown to form well‐defined aggregates with lithium __tert__‐butoxide (B) in tetrahydrofuran. The prevailing aggregates w