The electronic spectra of CT0 anions were observed in y-irradiated methylcyclohexane and MTHF glasses at 77 IC The band at 1386 nm in methylcyclohexane was assigned to C,. The spectrum in MTHF consisted of two bands at 1184 and 1377 nm. The former band was tentatively ascribed to C$,-and the latter
Anion radicals of acrylic monomers in γ-irradiated organic glasses at 77°K
✍ Scribed by Tomas Gillbro
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1973
- Tongue
- English
- Weight
- 173 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0887-6258
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📜 SIMILAR VOLUMES
ESR spectra of CsO radical anions were detected for &/MCHX and C,,/MTHF solid solutions which were y-irradiated at 77 K and subsequently annealed at 1 IO-140 K. The g-factors were 2.00 19 and 1.9997 for C,,JMCHX (or CJMCHX-d14) and CJMTHF, respectively. AH,,=O.26 mT was obtained for those solutions
## Radical pair formation in r&radiated chloroform at 77 K has been revealed by ESR spectra characteristic of triplet species, whereas no triplet spectra have been detected for other chlorinated methanes and bromoform. When solid-state radiolysis is performed on organic compounds at low temperatur