Anion-dependent modulations of DNA topoisomerase II-mediated reactions in potassium-containing solutions
β Scribed by Leonard A. Zwelling; Diana Chan; Michael Hinds; Lynn Silberman; Janice Mayes
- Book ID
- 117057834
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 780 KB
- Volume
- 152
- Category
- Article
- ISSN
- 0006-291X
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## The rates and activation energy parameters of halide ligand substitution in PdXf (X = Cl-, Br-), with N-alkyl substituted thioureas in aqueous halo acid solutions have been determined for the first kinetically distinguishable step. Ligand and product composition is substantiated by analytical dat
## Abstract The activation energy parameters for the reaction of PdX (X=Cl^β^, Br^β^) in aqueous halide acid solution with thiourea (tu) and selenourea (seu) have been determined. High rates of reaction parallel low enthalpies and appreciable negative entropy of activation. The rate law in each cas