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Anhydrous Lanthanide and Actinide(III) and (IV) Orthophosphates Mm(PO4)n. Synthesis, Crystallization, Structure, and Properties

✍ Scribed by A. I. Orlova; D. B. Kitaev

Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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## Abstract A new series of oxovanadium(IV)–lanthanide(III) heteronuclear complexes [Yb(H~2~O)~8~]~2~[(VO)~2~(TTHA)]~3~⋅21 H~2~O (1), {[Ho(H~2~O)~7~(VO)~2~(TTHA)][(VO)~2~(TTHA)]~0.5~}⋅ 8.5 H~2~O (2), {[Gd(H~2~O)~7~(VO)~2~(TTHA)][(VO)~2~(TTHA)]~0.5~}⋅8.5 H~2~O (3), {[Eu(H~2~O)~7~][(VO)~2~(TTHA)]~1.5