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Crystal Structures of Alkali-Metal Indium(III) Phosphates of [M3In(PO4)2]n (M = K, n = 10; M = Rb, n = 2) Compounds, and Band Structures and Chemical Bond Properties of [Rb3In(PO4)2]2 Crystal.

โœ Scribed by Yongchun Zhang; Wendan Cheng; Dongsheng Wu; Hao Zhang; Dagui Chen; Yajing Gong; Zigui Kan; Jing Zhu


Publisher
John Wiley and Sons
Year
2006
Weight
10 KB
Volume
37
Category
Article
ISSN
0931-7597

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Blue crystals of metal nitratocuprates(II), M 3 [Cu(NO 3 ) 4 ](NO 3 ) (M = K (I), NH 4 (II), Rb (III)) and Cs 2 [Cu(NO 3 ) 4 ] (IV) were synthesized from Cu(NO 3 ) 2 3 H 2 O and MNO 3 by heating at 100ยฑ140 ยฐC during 3ยฑ12 h. X-ray single crystal structures for isotypic I and II reveal the presence of