Anhydrous Lanthanide and Actinide(III) and (IV) Orthophosphates Mem(PO4)n. Synthesis, Crystallization, Structure, and Properties
โ Scribed by A. I. Orlova; D. B. Kitaev
- Book ID
- 106510849
- Publisher
- Springer
- Year
- 2005
- Tongue
- English
- Weight
- 156 KB
- Volume
- 47
- Category
- Article
- ISSN
- 1066-3622
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## Abstract A new series of oxovanadium(IV)โlanthanide(III) heteronuclear complexes [Yb(H~2~O)~8~]~2~[(VO)~2~(TTHA)]~3~โ 21โH~2~O (1), {[Ho(H~2~O)~7~(VO)~2~(TTHA)][(VO)~2~(TTHA)]~0.5~}โ 8.5โH~2~O (2), {[Gd(H~2~O)~7~(VO)~2~(TTHA)][(VO)~2~(TTHA)]~0.5~}โ 8.5โH~2~O (3), {[Eu(H~2~O)~7~][(VO)~2~(TTHA)]~1.5
## Abstract A series of new mixedโligand lanthanide complexes [Ln(hfa)~3~(4โcpyNO)]~2~ (Ln = Sm^III^โHo^III^ and Tm^III^; hfa^โ^ = hexafluoroacetylacetonate; 4โcpyNO = 4โcyanopyridine __N__โoxide) have been synthesised by treating the corresponding lanthanide hexafluoroacetylacetonates with 4โcpyNO