The "usual" implementation of the unimolecular rate constant in RRKM theory treats nonlinear molecules as pseudo-diatomits and thus does not conserve total angular momentum. A three-dimensional model for conservation of total angular momentum for vibrator transition states with the K rotational quan
Angular momentum conservation in photochemical fragmentation: A simple model
β Scribed by Donald Florida; Stuart A. Rice
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 510 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
We have studied the O Ο© OH 4 O 2 Ο© H reaction on Varandas's DMBE IV potential using a variety of statistical methods, all involving the RRKM assumption for the HO complex. \* 2 Comparing our results using microcanonical variational transition-state theory (VT) with those using microcanonical/fixed-
Analyse th6orique de la conservation de moment angulaire et de transmission de signal dans un senseur de taux de vitesse constante Theoretische Analyse der Erhaltung eines Winkelmoments und Signaltibertragung in einem Fiihler konstanter Geschwindigkeitsrate TeopeTn,-xecKn~ aHaJii43 coxpaHeHna yrstoB
The influence of the anisotropic polarizabilities of the neutral molecule on the lifetimes of complexes formed in ionmolecule collisions of Na+ with N2 and CO\* were determined using a classical trajectory calculation. Lifetimes are found to be increased substantiaIIy over those calculated for the s