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Anchimeric Assistance in Hydrogen Atom Transfer Reactions on the Side Chains of Amino Acid Derivatives

✍ Scribed by Easton, Christopher J.; Merrett, Martin C.


Book ID
127126539
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
100 KB
Volume
118
Category
Article
ISSN
0002-7863

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## Abstract Anchimerically assisted rearrangement, observed in the fluorination of some α‐amino acids with 70 : 30 (w/w) hydrogen fluoride/pyridine (by weight) in the presence of NaNO~2~, is substantially or fully suppressed by using the less acidic reagent 48 : 52 (w/w) hydrogen fluoride/pyridine.