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Analytical chemistry of benzilic acid

✍ Scribed by S. S. Gupta; D. Mukerjee

Book ID
112369016
Publisher
Springer
Year
1968
Tongue
English
Weight
369 KB
Volume
233
Category
Article
ISSN
1618-2650

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πŸ“œ SIMILAR VOLUMES

Chemistry of FK-506: Benzilic acid rearr
Chemistry of FK-506: Benzilic acid rearrangement of the tricarbonyl system
✍ D. Askin; R.A. Reamer; T.K. Jones; R.P. Volante; I. Shinkai πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 237 KB

Treatment of FK-506 with aqueous hydroxide results in a benzilic acid rearrangement of the C.8-c.10 tricarbonyl portion of the molecule. A corrected structure for a previously reported degradation product as well as oxidative decarboxylation of rearranged IX-506 is presented.