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Analysis of the vibrational fine structure in the electronic spectrum of the planar tetrachlorocuprate(II) ion in N-(2-ammonioethyl)morpholinium tetrachlorocuprate(II): evidence for a pseudo tetrahedral distortion in the 2A1g excited electronic state

โœ Scribed by McDonald, Robbie G.; Riley, Mark. J.; Hitchman, Michael A.

Book ID
126172008
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
976 KB
Volume
28
Category
Article
ISSN
0020-1669

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A system of "hot" bandsoriginating from the II= 1 level of the/& vibrational mode in the zpolarized 2A,,(z2)+2B,,(~Z-y\*) transition of the planar CuCB-ion of (methadonium),CuCl, is described. Their form suggests that the complex has a pseudo-.\_ tetrahedral geometry in the excited electronic state.