✦ LIBER ✦

Analysis of the relaxation response induced by various forms of pulse perturbation of coupled chemical equilibria

✍ Scribed by K. Tamura; Z.A. Schelly

Book ID: 103896750
Publisher: Elsevier Science
Year: 1982
Weight: 491 KB
Volume: 24
Category: Article
ISSN: 0378-4487
DOI: 10.1016/0378-4487(82)80059-9

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✦ Synopsis

In transient relaxation method studies of fast reactions, if the rate of response of the chemicil system is comparable with that+of the perturbation, the exact shape of the forcing function must be taken into account in the kinetic treatment of the relaxation response. An analysis of the transient response of multiple coupled equilibria using Laplace transform is presented for various forms of step or impulse perturbation. The method enables one to calculate the relaxation amplitudes for an unrestricted number of coupled chemical equilibria. Various aspects of the analysis of the relaxation response are discussed.

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