The mqnetx field etlcct upon the decay rate of the benzophenone betyl rsdrcal m rnrcellar solutaon ~3s stuched va nanosecond her photoi) srs Its decay IS represented by a comb~atron of two exponentrals The rate constant oi rhe slon component X\ZIS found to decrease from 1 6 Y IO6 s-' at zero field t
Analysis of the radical decay in a magnetic field by stochastic-Liouville equation
β Scribed by Keisuke Tominaga; Seigo Yamauchi; Noboru Hirota
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 475 KB
- Volume
- 179
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
A method for the simulation of the decay of the transient radical in a magnetic field is given by solving the stochastioLiouville equation numerically. The method is applied to analyze the decay of benzophenone ketyl radical in glycerol reported by Levin et al. It is suggested that the analysis of the decay by this method will provide information about the microscopic details of the geminate radical pairs.
π SIMILAR VOLUMES
## Abstract A magnetic field which is contained in a turbulent, electrically conducting fluid is supposed to decay. The decay time of the mean energy of the fluctuating part of the magnetic field β in contrast with the energy of the mean field β is shown to be determined by the molecular magnetic d
A variational solution is proposed for the integral equation form of the stochastic Liouville equations describing the radical pair mechanism of chemically induced electron polarization.