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Analysis of the epoxidation products of α-olefins with tertiary butyl hydroperoxide by IR spectroscopy

✍ Scribed by N. Kh. Shtivel'; V. A. Terent'ev; V. S. Markevich

Publisher
Springer US
Year
1971
Tongue
English
Weight
210 KB
Volume
15
Category
Article
ISSN
0021-9037

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Asymmetric epoxidation of hydrocarbon olefins by tert-butyl hydroperoxide with molybdenum(VI) catalysts in the presence of optically active diols. Application to the asymmetric synthesis of (3S)-2,3-oxidosqualene
✍ Kazuhide Tani; Masayoshi Hanafusa; Sei Otsuka 📂 Article 📅 1979 🏛 Elsevier Science 🌐 French ⚖ 209 KB

Catalytic enantioselective epoxidation of prochiral olefins without functional groups was achieved by tert-BuOOH using Mo(0)2(acac)2 -optically active diols as catalysts. In spite of dramatic developements in asymmetric hydrogenations using optically active transition metal catalysts during recent y