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Analysis of the crystal field in rare-earth substituted oxysulphide and vanadate systems

✍ Scribed by D.J. Newman; G.E. Stedman


Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
618 KB
Volume
32
Category
Article
ISSN
0022-3697

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Crystal field strength: Angular overlap
✍ M. Faucher; D. Garcia; C.K. JΓΈrgensen πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 English βš– 390 KB

An expression for the crystal field strength is defined in terms of one-electron energies and crystal field parameters. The relative contribution of kinetic energy and Coulombic interaction in ligand field effects is analyzed. The angular overlap model is applied to 11 rareearth or rareearthdoped co