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Crystal field effect in the thermal expansion of hexagonal rare earth compounds

✍ Scribed by B. Lüthi; H.R. Ott


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
274 KB
Volume
33
Category
Article
ISSN
0038-1098

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Crystal field strength: Angular overlap
✍ M. Faucher; D. Garcia; C.K. Jørgensen 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 390 KB

An expression for the crystal field strength is defined in terms of one-electron energies and crystal field parameters. The relative contribution of kinetic energy and Coulombic interaction in ligand field effects is analyzed. The angular overlap model is applied to 11 rareearth or rareearthdoped co