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Analysis of modern phenomenological approaches toward describing the structure and properties of the electrical double layer dense part on the metal solution interface

✍ Scribed by B.B. Damaskin; V.A. Safonov

Publisher: Elsevier Science
Year: 1997
Tongue: English
Weight: 776 KB
Volume: 42
Category: Article
ISSN: 0013-4686
DOI: 10.1016/s0013-4686(96)00343-x

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✦ Synopsis

In this paper the following issues are discussed: the components of the potential drop at the metal/solution interface and the corresponding components of the differential capacitance; the model interpretation of the metal/solution boundary without and with regard of the metal and solvent separate contributions; the Amokrane-Badiali model and its improvement when taking into account the chemisorptive interaction of solvent molecules with metals: and, finally. the development of views on the Volta's problem solution.

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Two types of solvent particles resident on the electrode surface have been considered: (1) associates of water molecules freely oriented aIong the electric field and (2) chemisorbed water dipoles oriented with the oxygen atom towards the metal surface. On the basis of this model, a semi-quantitative