An X-ray, spectroscopic and semiempirical quantum-mechanical study on complexes of thiones and selones with molecular diiodine
✍ Scribed by Cristiani, Franco; Demartin, Francesco; Devillanova, Francesco A.; Isaia, Franceso; Saba, Giuseppe; Verani, Gaetano
- Book ID
- 118127814
- Publisher
- The Royal Society of Chemistry
- Year
- 1992
- Tongue
- English
- Weight
- 910 KB
- Volume
- 24
- Category
- Article
- ISSN
- 1472-7773
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## Abstract 1,4,7‐Trithiacyclononane ([__9__]aneS~3~) reacts with molecular diiodine in CH~2~Cl~2~ to form a 1:1 adduct. The formation constant and the thermodynamic parameters of this adduct have been determined by UV‐visible spectra of several solutions at the temperatures of 15, 20, 25, 30, and
Cyclic diamide of o-phthalic acid with 3,6-dioxa-octyl-1,8-diamine (CPhDA) was synthesised by a new method and its hydrate structure has been studied by X-ray diVraction, FT-IR, NMR and PM5 semiempirical methods. The crystal of this compound is orthorhombic, space group Pbcn, with a D 16.7033(11), b