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An unusual way of the reaction of PI3with norbornene and norbornadiene

โœ Scribed by E. K. Beloglazkina; V. S. Tyurin; N. V. Zyk; Yu. K. Grishin

Book ID
105595863
Publisher
Springer
Year
1997
Tongue
English
Weight
386 KB
Volume
46
Category
Article
ISSN
1573-9171

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An unusual reaction of triphenylmethylsu
An unusual reaction of triphenylmethylsulfenyl chloride with norbornenf and norbornadiene
โœ Jacek M. Majewski; Janusz Zakrzewski ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 176 KB

Triphenylmethylsulfenyl chloride reacts with norbornene and norbornadiene to yield chlorodisulfides instead of the expected productschlorosulfides. The reaction of sulfenyl halides with alkenes is generally considered 1 follow an AdF2 mechanism . The formation of the bridged species sucF as: a-sulfu