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An unusual reaction of triphenylmethylsulfenyl chloride with norbornenf and norbornadiene

✍ Scribed by Jacek M. Majewski; Janusz Zakrzewski

Book ID: 104234318
Publisher: Elsevier Science
Year: 1981
Tongue: French
Weight: 176 KB
Volume: 22
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)81986-9

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✦ Synopsis

Triphenylmethylsulfenyl chloride reacts with norbornene and norbornadiene to yield chlorodisulfides instead of the expected productschlorosulfides. The reaction of sulfenyl halides with alkenes is generally considered 1 follow an AdF2 mechanism . The formation of the bridged species sucF as: a-sulfuranse 1, ion pairs 2-3 ion condition is belived to be undergo nucleophilic attack by step.

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