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An unusual relationship between the nitrogen-fluorine bond lengths and force constants in N-fluoroamines

โœ Scribed by Christen, Dines; Gupta, Om Dutt; Kadel, Johannes; Kirchmeier, Robert L.; Mack, Hans Georg; Oberhammer, Heinz; Shreeve, Jeanne M.


Book ID
121837468
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
582 KB
Volume
113
Category
Article
ISSN
0002-7863

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## Abstract The O๏ฃฟH bond length and the quadratic, cubic, and quartic stretching force constants, calculated __ab initio__ using the unscaled 4โ€31G basis set with full geometry optimization, are reported for 30 planar conformers of ten molecules contaning either the C๏ฃฟOH, N๏ฃฟOH, or O๏ฃฟOH group. The d