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An Unusual Organic–Inorganic Chain-like Hybrid Complex [(CuCl)2(o-phen)]∞ (o-phen=o-phenanthroline)

✍ Scribed by Shutao Wang; Yangguang Li; Enbo Wang; Guoyou Luan; Changwen Hu; Ninghai Hu; Hengqing Jia

Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
246 KB
Volume
167
Category
Article
ISSN
0022-4596

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✦ Synopsis

A novel organic-inorganic hybrid complex [(CuCl) 2 (o-phen)] N 1 (o-phen=o-phenanthroline) has been hydrothermally synthesized and structurally characterized by elemental analyses, XPS spectrum, TG analysis, and single-crystal X-ray diffraction. Compound 1 crystallizes in the monoclinic system, space group P2 1 /n, a=3.7285(7

.0643 for 2559 reflections). Data were collected on an R-axis RAPID diffractometer at 293 K in the range of 1.60oho27.481. The title compound exhibits a one-dimensional chain-like scaffolding constructed by the unusual [Cu 3 Cl 3 ] hexagon motifs by sharing opposite edges. Only Cu(1) sites of the [Cu 3 Cl 3 ] hexagon are coordinated with N donors of o-phen groups. Furthermore, the three-dimensional supermolecular architecture is formed by C-HyCl hydrogen bonds between o-phen groups and CuCl chains.

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