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An Unusual Intramolecular Diels-Alder Reaction in the Photoöxidation of a (Furano) Heterocyclophane

✍ Scribed by Wasserman, Harry H.; Doumaux, Arthur R.

Book ID
126818761
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
274 KB
Volume
84
Category
Article
ISSN
0002-7863

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✍ L.H. Klemm; K.W. Gopinath 📂 Article 📅 1963 🏛 Elsevier Science 🌐 French ⚖ 135 KB

Y-AP~PICROP~D~PI~YLLIN (II) was isolated as a secondary degradation product resulting from dehydration of the naturally occurring, tumor-necrotizing compound podophyllotoxln. 1 II was found to be identical with a compound previously synthesized by Haworth and Richardson2 by a multiple-step procedure