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Characterization of the Switch in the Mechanism of an Intramolecular Diels−Alder Reaction

✍ Scribed by López, Carlos Silva; Faza, Olalla Nieto; de Lera, Angel R.


Book ID
126253537
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
479 KB
Volume
73
Category
Article
ISSN
0022-3263

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A mechanistic investigation into the recently reported intramolecular aryl Diels-Alder reaction was carried out using deuterium labeling. These studies led to the conclusion that the initial Diels-Alder adduct is isomerized to a highly conjugated tetra-ene intermediate which undergoes a stereospecif