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An unusual erythrolide containing a bicyclo [9.2.1.] tetradecane skeleton

✍ Scribed by Daryl Banjoo; Anderson R. Maxwell; Baldwin S. Mootoo; Alan J. Lough; Stewart McLean; William F. Reynolds


Book ID
108386493
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
184 KB
Volume
39
Category
Article
ISSN
0040-4039

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6,9-Dihydro-6,9-ethenocycloheptalgh]phenalen-l-one (A) has been svnthesized startine from the Diels-Alder adduct 161 of acepleiadiene ( 5) and maleic anhydride through 10 stepsast\rith reasonable yields. Spectroscopic properties of & suggested the intramolecular electron supply from the remote ethyl