The cooperativity between a radical and a transition-metal ion in a single molecular entity is demonstrated in highly sophisticated biocatalysts.
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An Unprecedented Bridging Phenoxyl Radical in Dicopper(II) Complexes: Evidence for an S=3/2 Spin State
✍ Scribed by Fabien Michel; Stéphane Torelli; Fabrice Thomas; Carole Duboc; Christian Philouze; Catherine Belle; Sylvain Hamman; Eric Saint-Aman; Jean-Louis Pierre
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 128 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0044-8249
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📜 SIMILAR VOLUMES
An Unprecedented Bridging Phenoxyl Radic
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Fabien Michel; Stéphane Torelli; Fabrice Thomas; Carole Duboc; Christian Philouz
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Article
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2005
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⚖ 127 KB
Titelbild: An Unprecedented Bridging Phe
✍
Fabien Michel; Stéphane Torelli; Fabrice Thomas; Carole Duboc; Christian Philouz
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Article
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2005
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John Wiley and Sons
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⚖ 88 KB
Cover Picture: An Unprecedented Bridging
✍
Fabien Michel; Stéphane Torelli; Fabrice Thomas; Carole Duboc; Christian Philouz
📂
Article
📅
2005
🏛
John Wiley and Sons
🌐
English
⚖ 87 KB
**Metal–radical interactions** are at the heart of many biocatalysts that contain transition metals. The cover picture shows the structure of a dicopper(II) complex in which a phenoxyl radical bridges the metal centers. The three spins are ferromagnetically coupled, as the black arrows indicate. In
Evidence for an Unusual Thermally Induce
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