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An Unprecedented Bridging Phenoxyl Radical in Dicopper(II) Complexes: Evidence for an S=3/2 Spin State

✍ Scribed by Fabien Michel; Stéphane Torelli; Fabrice Thomas; Carole Duboc; Christian Philouze; Catherine Belle; Sylvain Hamman; Eric Saint-Aman; Jean-Louis Pierre

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
127 KB
Volume
117
Category
Article
ISSN
0044-8249

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✦ Synopsis

The cooperativity between a radical and a transition-metal ion in a single molecular entity is demonstrated in highly sophisticated biocatalysts.

📜 SIMILAR VOLUMES

Cover Picture: An Unprecedented Bridging
Cover Picture: An Unprecedented Bridging Phenoxyl Radical in Dicopper(II) Complexes: Evidence for an S=3/2 Spin State (Angew. Chem. Int. Ed. 3/2005)
✍ Fabien Michel; Stéphane Torelli; Fabrice Thomas; Carole Duboc; Christian Philouz 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 87 KB

**Metal–radical interactions** are at the heart of many biocatalysts that contain transition metals. The cover picture shows the structure of a dicopper(II) complex in which a phenoxyl radical bridges the metal centers. The three spins are ferromagnetically coupled, as the black arrows indicate. In

Evidence for an Unusual Thermally Induce
Evidence for an Unusual Thermally Induced Low-Spin (S=1/2) ⇄ Intermediate-Spin (S=3/2) Transition in a Six-Coordinate Iron(III) Complex: Structure and Electronic Properties of a (1,2-Benzenedithiolato)iron(III) Complex Containing N,N′-Dimethyl-2,11-diaza[3.3](2,6)pyridinophane as Ligand
✍ Welf O. Koch; Volker Schünemann; Michael Gerdan; Alfred X. Trautwein; Hans-Jörg 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 150 KB 👁 2 views