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An Unprecedented Bending of a Bridging Diynyl Ligand in an Unsymmetrical Binuclear Rhodium(I) Complex

โœ Scribed by Werner, Helmut; Gevert, Olaf; Steinert, Paul; Wolf, Justin

Book ID
127297947
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
636 KB
Volume
14
Category
Article
ISSN
0276-7333

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Photophysics of a flexible ligand bridge
Photophysics of a flexible ligand bridged rhodium(I) dimer: An excited state conformational change in a crystalline solid
โœ Richard L. Blakley; Yan Yin; Charles Lloyd; Joel T. Mague; Gary L. McPherson ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 439 KB

The dimeric Rh(I) complex, Rh,(PNP)$+ (where PNP= CH,N [ P(OCH,),],). adopts a flexible "basket" type structure. The solid state phosphorescence from the (C6H&B-salts of the dimeric complex (two crystallographic forms) indicates a thermally activated conformational change in the triplet excited stat