An Unexpected Transformation of Benzyl Carbamates into α-azidobenzeneacetamides
✍ Scribed by Christoph Strässler; Heinz Heimgartner
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- German
- Weight
- 464 KB
- Volume
- 80
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Treatment of 5c with LDA and diphenyl phosphorazidate (DPPA) also yielded 6c (44%)
📜 SIMILAR VOLUMES
An interesting and surprising rearrangement was observed during the reaction of 4-N-benzyl piperazinone derivatives with Lawesson's reagent as a thionating agent. Investigation into the possible mechanism responsible for these results is reported herein.
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