An unexpected product: di-μ-iodo-bis{[2-(N-diphenylphosphinomethyl-N-cyclohexylamino)pyridine]iodomercury(II)}

{μ-9,10-Bis[(n-propylamino)methyl]an

{μ-9,10-Bis[(n-propylamino)methyl]anthracene-κ2N:N′}bis{bis[6-chloro-2-(diphenylphosphino)pyridine-κP]copper(I)} diperchlorate

✍ Xu, Feng-Bo ;Xu, Hu ;Leng, Xue-Bing ;Song, Hai-Bin ;Li, Qing-Shan ;Zou, Ru-Yi ;Z 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 304 KB

The title compound, [Cu 2 (C 15 H 13 ClP) 4 (C 30 H 28 N 2 )](ClO 4 ) 2 , was synthesized by the reaction of 9,10-bis[(n-propylamino)methyl]anthracene and 6-chloro-2-(diphenylphosphino)pyridine with [Cu(CH 3 CN) 4 ]ClO 4 . The Cu atoms adopt a trigonal±planar geometry and the cation is centrosymmetr

An unexpected product: di-μ-iodo-bis{[2-(N-di­phenyl­phosphino­methyl-N-cyclo­hexyl­amino)­pyridine]­iodo­mercury(II)}

An unexpected product: di-μ-iodo-bis{[2-(N-diphenylphosphinomethyl-N-cyclohexylamino)pyridine]iodomercury(II)}