Ring-opening of oxiranes 1 by the silicon-and sulfur-phenylthiofurans 5 is achieved by reaction with palladium(II) acetate. The corresponding furans 7 are obtained when functionalized propargyl anions 2 yields the corresponding alk-4-yn-1-ols 3. Cyclization of 3 to 2,3-dihydro-4-copper(II) chloride
β¦ LIBER β¦
An Unexpected Palladium-Catalyzed Cyclization of Bis-Hydroxy Allylic Alcohols to Dioxabicylo[2.2.2]octanes.
β Scribed by Anna Zawisza; Denis Sinou
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 21 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
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