𝔖 Bobbio Scriptorium
✦   LIBER   ✦

An Unexpected Diboroxane: Crystal Structure of Me2HN · (CF3)2BOB(CF3)2 · NHMe2

✍ Scribed by David J. Brauer; Silke Buchheim-Spiegel; Hans Bürger; Gottfried Pawelke


Publisher
John Wiley and Sons
Year
2002
Tongue
German
Weight
82 KB
Volume
628
Category
Article
ISSN
0372-7874

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Photoelectron-Spectrum and Electronic St
✍ Stefan Reinemann; Rolf Minkwitz; Klaus Kowski; Paul Rademacher 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 170 KB 👁 1 views

The electronic structure of the title compound 1 has been third highest occupied MO is mainly localized at the oxygen atom (n 0 ). All calculations indicate that the molecule has a investigated by UV photoelectron spectroscopy and quantum chemical calculations. 1 has two nearly degenerate n N lone-t

Barium, Potassium, and Tris(ethane-1,2-d
✍ Carmel T. Abrahams; Rachel Blackshaw; Glen B. Deacon; Bryan M. Gatehouse; Gerald 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 German ⚖ 215 KB 👁 2 views

The barium perfluoroalkanedisulfonates Ba(O 3 S) 2 (CF 2 ) n (n = 1, 3±5) and the new potassium fluoroalkanedisulfonates K 2 (O 3 S) 2 CHF, K 2 (O 3 S) 2 CF 2 , and K 2 (O 3 S) 2 (CF 2 ) 5 have been prepared by reaction of (CF 2 ) n (SO 2 F) 2 (n = 1, 3±5) or CHF(SO 2 F) 2 with CaO (or Ca(OH) 2 ) an

New Azoniaboratacyclopropanes from (F3C)
✍ David J. Brauer; Hans Bürger; Silke Buchheim-Spiegel; Gottfried Pawelke 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 172 KB

Dimethyl-2,2-bis(trifluoromethyl)azoniaboratacyclo-HC(N 2 )C(=O)OtBu react with 1 to form three-membered rings, which hydrolyze rapidly to form Me 2 NH-CR 1 R 2 -propanes, cyclo-(F 3 C)

[2+4] and [2+2] Cycloaddition Reactions
✍ David J. Brauer; Hans Bürger; Gottfried Pawelke; Jürgen Rothe 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 86 KB 👁 1 views

N-sulfinylacylamides R-C(ϭO)-NϭSϭO react with (CF 3 ) 2 BNMe 2 (1) to form, by [2ϩ4] cycloaddition, six-membered rings cyclo-(CF 3 ) 2 B-NMe 2 -S(ϭO)-NϭC(R)-O for R ϭ Me (2), t-Bu (3), C 6 H 5 (4), and p-CH 3 C 6 H 4 (5) while N-sulfinylcarbamic acid esters R-O-C(ϭO)-NϭSϭO react with 1 to yield mixt