An Unexpected Diboroxane: Crystal Structure of Me2HN · (CF3)2BOB(CF3)2 · NHMe2
✍ Scribed by David J. Brauer; Silke Buchheim-Spiegel; Hans Bürger; Gottfried Pawelke
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- German
- Weight
- 82 KB
- Volume
- 628
- Category
- Article
- ISSN
- 0372-7874
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The electronic structure of the title compound 1 has been third highest occupied MO is mainly localized at the oxygen atom (n 0 ). All calculations indicate that the molecule has a investigated by UV photoelectron spectroscopy and quantum chemical calculations. 1 has two nearly degenerate n N lone-t
The barium perfluoroalkanedisulfonates Ba(O 3 S) 2 (CF 2 ) n (n = 1, 3±5) and the new potassium fluoroalkanedisulfonates K 2 (O 3 S) 2 CHF, K 2 (O 3 S) 2 CF 2 , and K 2 (O 3 S) 2 (CF 2 ) 5 have been prepared by reaction of (CF 2 ) n (SO 2 F) 2 (n = 1, 3±5) or CHF(SO 2 F) 2 with CaO (or Ca(OH) 2 ) an
Dimethyl-2,2-bis(trifluoromethyl)azoniaboratacyclo-HC(N 2 )C(=O)OtBu react with 1 to form three-membered rings, which hydrolyze rapidly to form Me 2 NH-CR 1 R 2 -propanes, cyclo-(F 3 C)
N-sulfinylacylamides R-C(ϭO)-NϭSϭO react with (CF 3 ) 2 BNMe 2 (1) to form, by [2ϩ4] cycloaddition, six-membered rings cyclo-(CF 3 ) 2 B-NMe 2 -S(ϭO)-NϭC(R)-O for R ϭ Me (2), t-Bu (3), C 6 H 5 (4), and p-CH 3 C 6 H 4 (5) while N-sulfinylcarbamic acid esters R-O-C(ϭO)-NϭSϭO react with 1 to yield mixt