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Photoelectron-Spectrum and Electronic Structure of Perfluoro(2,4-dimethyl-3-oxa-2,4-diazapentane) (CF3)2N–O–N(CF3)2

✍ Scribed by Stefan Reinemann; Rolf Minkwitz; Klaus Kowski; Paul Rademacher

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 170 KB
Volume: 1998
Category: Article
ISSN: 1434-1948
DOI: 10.1002/(sici)1099-0682(199810)1998:10<1377::aid-ejic1377>3.0.co;2-b

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✦ Synopsis

The electronic structure of the title compound 1 has been third highest occupied MO is mainly localized at the oxygen atom (n 0 ). All calculations indicate that the molecule has a investigated by UV photoelectron spectroscopy and quantum chemical calculations. 1 has two nearly degenerate n N lone-twisted C 2 conformation. pair orbitals which form the two highest occupied MOs. The

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