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An oxidative metabolite of perillaldehyde from Perilla frutescens

✍ Scribed by Masahiro Tada; Risa Matsumoto; Kazuhiro Chiba


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
141 KB
Volume
43
Category
Article
ISSN
0031-9422

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## Abstract The first β€œopen chain” representative of the palmarumycins, the biaryl ether 1, was isolated from __Coniothyrium palmarum__. Phenol oxidation of 1 with silver oxide as a model for a biosynthetic step yielded 4 with the usual spiroacetal structure of the palmarumycins. The absolute (__S_