𝔖 Bobbio Scriptorium
✦   LIBER   ✦

An Oxidation and Ring Contraction Approach to the Synthesis of (±)-1-Deoxynojirimycin and (±)-1-Deoxyaltronojirimycin

✍ Scribed by Bagal, Sharan K.; Davies, Stephen G.; Lee, James A.; Roberts, Paul M.; Russell, Angela J.; Scott, Philip M.; Thomson, James E.

Book ID
111696167
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
274 KB
Volume
12
Category
Article
ISSN
1523-7060

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

ChemInform Abstract: A New Approach to 1
ChemInform Abstract: A New Approach to 1-Deoxy-azasugars: Asymmetric Synthesis of 1- Deoxymannojirimycin and 1-Deoxyaltronojirimycin.
✍ Y.-M. XU; W.-S. ZHOU 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB 👁 2 views

The key step in this concise and flexible method for the synthesis of biologically interesting piperidine alkaloids such as 1-deoxy-azasugars (VII) and (X) is the kinetic asymmetric resolution under modified Sharpless conditions to compounds (S)-(I) and (II). It is noteworthy that the synthesis of t

The Synthesis of 6-Azido and 6-Amino Ana
The Synthesis of 6-Azido and 6-Amino Analogues of 1-Deoxynojirimycin and their Conversion to Bicyclic Derivatives
✍ Amuri Kilonda; Frans Compernolle; Koen Peeters; Gert J Joly; Suzanne Toppet; Geo 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 214 KB

1-Amino-1-deoxy-d-glucitol (14) was converted to the N-Boc-2,3;5,6-di-O-isopropylidene derivative 16 which was transformed further into the selectively protected 2,3-O-isopropylidene 6-azido piperidine 3. The synthesis proceeded via a double inversion at C-5 involving internal attack of 4-OH to form