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An NMR and ESR-investigation of the catalytic system Ni(acac)2, C3H4, (i-Bu)3Al for the polymerization of propadiene

✍ Scribed by J.G. van Ommen; J.G.M. van Rens; P.J. Gellings


Publisher
Elsevier Science
Year
1981
Weight
510 KB
Volume
13
Category
Article
ISSN
0304-5102

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The reaction of (C,(CH,),)Ti(CHZC6H,), with B(C,F,), in chlorobenzene at 25 "C produces a mixture of [(C,(CH,)5 )Ti(CH,C,H,),] + [B(CH2C6H5)(C6F,),] -(1) and Ti(II1) complexes which have been characterized by NMR and electron spin resonance (ESR) spectroscopy, respectively. Spectroscopic data combin