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An MC-SCF study of [1,3] and [1,2] sigmatropic shifts in propene

โœ Scribed by Bernardi, Fernando; Robb, Michael A.; Schlegel, H. Bernhard; Tonachini, Glauco

Book ID
121367231
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
622 KB
Volume
106
Category
Article
ISSN
0002-7863

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โœ Oleg N. Chupakhin; Valery N. Kozhevnikov; Dmitry N. Kozhevnikov; Vladimir L. Rus ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 122 KB

The reaction of 3-pyrrolidino-l,2,4-triazine 4-oxide with ammonia leads to the product of tele-substitution of pyrrolidine -5-amino-1,2,4-triazine 4-oxide. Sigmatropic shift of hydrogen postulated for such reactions has been proved by isolation of key intermediates.